Ordered Amorphous Carbon: New Ordered Structure of Amorphous Carbon Clusters Induced by Fullerene-Cubane Reactions (Adv. Mater. 22/2018)

Highly Ordered Amorphous Silicon-Carbon Alloys Obtained by RF PECVD

We have shown that close to stoichiometry RF PECVD amorphous silicon carbon alloys deposited under silane starving plasma conditions exhibit a tendency towards c-SiC chemical order. Motivated by this trend, we further explore the e ect of increasing RF power and H2 dilution of the gaseous mixtures, aiming to obtain the amorphous counterpart of c-SiC by the RF-PECVD technique. Doping experiments...

Long-range ordered carbon clusters: a crystalline material with amorphous building blocks.

Solid-state materials can be categorized by their structures into crystalline (having periodic translation symmetry), amorphous (no periodic and orientational symmetry), and quasi-crystalline (having orientational but not periodic translation symmetry) phases. Hybridization of crystalline and amorphous structures at the atomic level has not been experimentally observed. We report the discovery ...

Thermal decomposition of fullerene nanowhiskers protected by amorphous carbon mask

Fullerene nanostructures are well known for their unique morphology, physical and mechanical properties. The thermal stability of fullerene nanostructures, such as their sublimation at high temperature is also very important for studying their structures and applications. In this work, We observed fullerene nanowhiskers (FNWs) in situ with scanning helium ion microscopy (HIM) at elevated temper...

The Electronic Structure of Amorphous Carbon Nanodots.

We have studied hydrogen-passivated amorphous carbon nanostructures with semiempirical molecular orbital theory in order to provide an understanding of the factors that affect their electronic properties. Amorphous structures were first constructed using periodic calculations in a melt/quench protocol. Pure periodic amorphous carbon structures and their counterparts doped with nitrogen and/or o...

Thermally induced evolution of hydrogenated amorphous carbon